Professor Green, Rod Stewart, and Love Island's Jack Fincham also attended the swanky event.
Reality star Vicky Pattison oozed sophistication in a checked trouser suit, with the Apprentice's Karren Brady also opting for a chic blazer teamed with a pair of black trousers and a lace-trimmed vest top.
Meanwhile, actress Michelle Heaton looked glamorous in a long-sleeved red dress that exposed her bare shoulders.
Rocker Rod Stewart had to opt for a more unusual style choice – pairing his on-trend leopard print suit jacket and shoes with a grey leg brace following a nasty fall last month.
Last week, the 73-year-old revealed that he fell on a "great big lump of concrete" while playing with his two youngest sons, 12-year-old Alistair, and seven-year-old Aiden – badly injuring his foot.
However, Rod's wife, Penny Lancastar, looked as stunning as ever at tonight's awards – supporting her husband in a bright pink jacket and black lace dress.
TV presenter Lorraine Kelly also hit the red carpet – showing off her trim figure in a fitted navy dress with simple zip detailing.
Jack Fincham looked handsome in a tweed jacket with a silk scarf – attending the do without his Love Island girlfriend, Dani Dyer.
His co-star Dr. Alex George, radio host Chris Evans, and former-X Factor star Chico Slimani were also at the ceremony.
Tonight marks The Sun's second annual Who Cares Wins health awards – taking place in the year of the NHS’s 70th birthday.
It is a chance for Sun readers to pay tribute to their health heroes – the doctors, nurses, midwives, volunteers and other medical staff who have saved their lives or cared for their loved ones.
Rapper Professor Green was among the celebrities to present the winners with their award – honouring this year's Mental Health Hero Mary, Mitchell.
The 71-year-old good samaritan was nominated by the daughter of her best friend for opening up her home to patients with mental health conditions – giving them a place to stay for months after being discharged from hospital.
Professor Green has always been open about his own mental health battle, suffering from depression and anxiety.
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