The couple, who rekindled their romance earlier this year, looked very much in love as they walked the carpet at the Gala for the Global Ocean at the Opera of Monte-Carlo in Monaco together.
Katy, 33, wore a tan-coloured gown, complete with sleeves that resembled the outer shell of a disco ball whilst Orlando, 41, looked sharp in a suit.
The famous duo have previously attended events together but they have never posed up on a red carpet before.
Earlier today the singer delighted fans when she shared a video of Orlando, showing their very flirty relationship.
At one point the words “Lemme touch ur butt” flashed up when he turned around and she later could be heard saying: “Will you show me your trunk baby… turn around.”
Meanwhile, Orlando recently admitted that their romance came as a "complete surprise" to him but says they have a "remarkable connection".
He explained: "It is a very odd one. She's a remarkable human being, actually. Completely surprising, because I am not her demographic.
"I am a little older than her, so I wasn't someone overly familiar with her artistic endeavours when we met. I wouldn't have imagined anything happening. And, you know, when you get hit sideways you get hit sideways."
The actor, who was previously married to Miranda Kerr, continued: "You don't pick who you fall in love with. And then you come around and there's all sorts of things that happen in between, right?
"We had a really remarkable connection. And it's difficult. She's on tour, I'm doing a play, everything evolves. I have a lot of respect for her and a lot of deep feeling. So we will see."
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