The married star, 51, sent one starstruck fan a photo of himself lying topless in bed beside hotel note paper with her initials on it.
He told the mum of three, 31, he found it a turn on that she wanted to ask for a signed T-shirt.
The darts fan said: "I felt a bit starstruck and I told him I was married for eight years and had three kids but he wasn't fazed.
"All he wanted to do was meet up anytime anywhere. It was crazy. I thought it was a wind-up but he sent me a voice message and selfies from hotel rooms.
"The stuff he was sending was sleazy. I told him that I was happily married thank you very much.
"I always thought he was a nice family man. Me and my husband used to be big fans of Barney but not now.
"It was sleazy it was horrible. I'm clearly not the only one. He's the Tiger Woods of darts."
Van Barneveld also pestered a walk-on girl, 27, for a date.
The model described how Barney made a smutty remark backstage then tracked her down on Instagram to tell her she looked "fantastic" and asked her out on a date.
When the brunette model, who asked not to be named, replied she could only be friends, the married dad-of-three replied 'fair enough, goodbye' and deleted her as a contact.
The model told The Sun: “He thinks because he’s got a bit of money and a bit of fame he can prey on girls half his age can get any girl he wants.
“But he’s twice my age and twice my weight."
The latest revelations come after The Sun published pictures of the Dutch ace kissing a woman outside a hotel.
It also emerged that he and wife Silvia, 52, were divorcing after 25 years of marriage. His new lover was named as Julia Evans, 34, from West London.
His spokesman said she was a “respected manager” and not involved in darts.
He added: “According to Barney, this is a serious relationship.”
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