The United legend was pictured leaving San Carlo Italian restaurant in Manchester, dressed in a black leather jacket, dark jeans, white trainers and a flatcap.
Fans ambushed Becks outside of the restaurant and begged him for photos before he was escorted into a taxi.
Beckham, 43, who dodged a £200,000 speeding fine last week, dined out with Class of 92 team-mates Neville and Giggs, as well as Valencia owner Peter Lim.
Sky Sports pundit Neville, 43, dressed casual in a blue bodywarmer, a pair of blue jeans and trainers, and was snapped checking his phone as he left the restaurant.
Neville knows Valencia owner Lim well from his four-month spell in charge of the Spanish club.
Despite getting the sack after a disastrous half-season, the pair maintain a good relationship.
The former United stars, who boast five Champions League titles between them, will be hoping Jose Mourinho's men can do the business over the La Liga club tonight at Old Trafford.
United are top of Group H after their 3-0 win over Young Boys but still face tough tests against Valencia and Juventus.
They are in desperate need of a win tonight after suffering back-to-back defeats in the Carabao Cup and Premier League to Derby and West Ham.
Mourinho, who is warring with star duo Paul Pogba and Alexis Sanchez, warned his squad he expects 100 per cent from them tonight as no player is bigger than the club.
He said: "All my life I have followed certain golden rules. A team can lose matches but never, ever its dignity.
"It must fight, work, compete, win duels, be humble. At end of every game players must be exhausted because of hard work for club, fans plus each other.
"The team is always more important than individual. Crest on chest more important than name on shirt. This is me. This is how I work. This is what I ask of my team, my group, my club."
Valencia boss Marcelino, meanwhile, believes United will struggle defensively against them.
He said: "We will try to counteract their play with a collective effort. They are powerful in duels, but they struggle to defend collectively.
"We will win if we play well. Is it a good time to play them? Who knows. We know we are facing a difficult opponent, maybe they are not in their best moment, but it could be similar for us."
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